There aren’t many men who can laugh about being the “most hated man in the world,” but then most men aren’t able to deceive Sandra Bullock - and most others - for so long.

During Jesse James’ upcoming interview with Nightline, the 41-year-old admits he “took a pretty amazing life and amazing success and marriage ... and threw it away.”

But what does Jesse have to say about all the compliments Sandra Bullock showered on him during awards season? And what about those mistresses—did he consider them “love affairs”? Find out when James’ chat with Vicki Mabrey airs next Tuesday at 11:35pm.